Composite Hydrophobic Modification of Expanded Perlite

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Title: Composite Hydrophobic Modification of Expanded Perlite

Author(s): Qiuhui Yan, Haojie Wang, Jieren Luo, Ye Lin, and Yaxin Yang

Publication: Materials Journal

Volume: 119

Issue: 1

Appears on pages(s): 71-78

Keywords: composite modification; expanded perlite (EP); hydrophobic modification; orthogonal test; vacuum modification

DOI: 10.14359/51733148

Date: 1/1/2022

Abstract:
The hydrophobic agents polydimethylsiloxane emulsion (BS 1042) and sodium methyl silicate were used to modify expanded perlite (EP). The effects of the hydrophobic agents and modification methods on the water absorption, thermal conductivity, and bulk density of EP were investigated. First, the orthogonal experiments of the two hydrophobic agents on the modification of EP were designed, and the effects of the drying temperature, hydrophobic concentration, soaking time, and soaking temperature on the performance of EP were analyzed. The optimum modification conditions for the two hydrophobic agents were obtained. Second, under the optimum conditions, the EP was modified by BS 1042 under vacuum conditions and then modified by the atmospheric pressure with sodium methyl silicate, so the composite-modified EP with excellent hydrophobic performance was obtained. The results showed that the water absorption of the composite modified EP was significantly reduced, from 390.1 to 16.2%; the thermal conductivity increased from 0.0532 to 0.0555 w/(m·k), with a small increase of only 4.3%; and the bulk density increased from 51.6 to 59.2 kg/m3, with an increase of 14.7%.

Related References:

1. Raji, M.; Nekhlaoui, S.; El Amrani El Hassani, I.-E.; Essassi, E. M.; Essabir, H.; Rodrigue, D.; Bouhfid, R.; and Qaiss, A., “Utilization of Volcanic Amorphous Aluminosilicate Rocks (Perlite) as Alternative Materials in Lightweight Composites,” Composites Part B: Engineering, V. 165, May 2019, pp. 47-54.

2. Shastri, D., and Kim, H. S., “A New Consolidation Process for Expanded Perlite Particles,” Construction and Building Materials, V. 60, June 2014, pp. 1-7.

3. Sengul, O.; Azizi, S.; Karaosmanoglu, F.; and Tasdemir, M. A., “Effect of Expanded Perlite on the Mechanical Properties and Thermal Conductivity of Lightweight Concrete,” Energy and Buildings, V. 43, No. 2-3, Feb.-Mar. 2011, pp. 671-676. doi: 10.1016/j.enbuild.2010.11.008

4. Kotwica, Ł.; Pichór, W.; Kapeluszna, E.; and Różycka, A., “Utilization of Waste Expanded Perlite as New Effective Supplementary Cementitious Material,” Journal of Cleaner Production, V. 140, Part 3, Jan. 2017, pp.1344-1352.

5. Gürsoy, M., and Karaman, M., “Improvement of Wetting Properties of Expanded Perlite Particles by an Organic Conformal Coating,” Progress in Organic Coatings, V. 120, July 2018, pp. 190-197.

6. Liu, Y.; Ma, C.; Wang, D.; Wang, Y.; and Liu, J., “Nonlinear Effect of Moisture Content on Effective Thermal Conductivity of Building Materials with Different Pore Size Distributions,” International Journal of Thermophysics, V. 37, No. 6, June 2016, Article No. 56. doi: 10.1007/s10765-016-2062-0

7. Papa, E.; Medri, V.; Natali Murri, A.; Laghi, L.; De Aloysio, G.; Bandini, S.; and Landi, E., “Characterization of Alkali Bonded Expanded Perlite,” Construction and Building Materials, V. 191, Dec. 2018, pp. 1139-1147. doi: 10.1016/j.conbuildmat.2018.10.086

8. Arifuzzaman, M., and Kim, H. S., “Novel Mechanical Behaviour of Perlite/Sodium Silicate Composites,” Construction and Building Materials, V. 93, Sept. 2015, pp. 230-240.

9. Yan, Q.; Lu, T.; Luo, J.; Hou, Y.; and Nan, X., “Exergy Cascade Release Pathways and Exergy Efficiency Analysis for Typical Indirect Coal Combustion Processes,” Combustion Theory and Modelling, V. 23, No. 6, 2019, pp. 1134-1149. doi: 10.1080/13647830.2019.1639826

10. Allouzi, R.; Qatawna, A. A.; and Al-Kasasbeh, T., “Lightweight Foamed Concrete Mixture for Structural Use,” ACI Materials Journal, V. 117, No. 3, May 2020, pp. 99-109.

11. Wei, J.; Zhang, Q.; Zhao, L.; Hao, L.; and Yang, C., “Enhanced Thermoelectric Properties of Carbon Fiber Reinforced Cement Composites,” Ceramics International, V. 42, No. 10, Aug. 2016, pp. 11568-11573. doi: 10.1016/j.ceramint.2016.04.014

12. Xie, Y.-D.; Lin, X.-J.; Ai, H.-H.; and Ji, T., “Effect of Expanded Perlite or Expanded Vermiculite on Performance of Magnesium Potassium Phosphate Cement-Based Refractory,” ACI Materials Journal, V. 117, No. 3, May 2020, pp. 217-223.

13. Zhu, H. X.; Zhang, L.; and Sun, S. J., etal., “Application of Silicone Hydrophober in Thermal Mortar,” New Building Materials, V. 36, No. 7, 2009, pp. 15-17. (in Chinese)

14. Ye, X. D.; Guo, Y. X.; Jia, Y. C.; Ye, X.; Wang, S.; Cai, A. J.; Wu, X. J.; and Shao, J. Y., “A Facile Method to Fabricate Surfaces Showing Superhydrophilicity in Air and Superhydrophobicity in Oil,” Science China Technological Sciences, V. 60, No. 11, Nov. 2017, pp. 1724-1731. doi: 10.1007/s11431-017-9074-y

15. Huang, R.; Feng, J.; Ling, Z.; Fang, X.; and Zhang, Z., “A Sodium Acetate Trihydrate-Formamide/Expanded Perlite Composite with High Latent Heat and Suitable Phase Change Temperatures for Use in Building Roof,” Construction and Building Materials, V. 226, Nov. 2019, pp. 859-867. doi: 10.1016/j.conbuildmat.2019.07.331

16. Li, X.; Chen, H.; Liu, L.; Lu, Z.; Sanjayan, J. G.; and Duan, W. H., “Development of Granular Expanded Perlite/Paraffin Phase Change Material Composites and Prevention of Leakage,” Solar Energy, V. 137, Nov. 2016, pp. 179-188. doi: 10.1016/j.solener.2016.08.012

17. Ramakrishnan, S.; Wang, X.; and Sanjayan, J., “Thermal Enhancement of Paraffin/Hydrophobic Expanded Perlite Granular Phase Change Composite Using Graphene Nanoplatelets,” Energy and Buildings, V. 169, June 2018, pp. 206-215. doi: 10.1016/j.enbuild.2018.03.053

18. Zhang, G.; Li, G.; and Li, Y., “Effects of Superplasticizers and Retarders on the Fluidity and Strength of Sulphoaluminate Cement,” Construction and Building Materials, V. 126, Nov. 2016, pp. 44-54. doi: 10.1016/j.conbuildmat.2016.09.019

19. Gürsoy, M., and Karaman, M., “Hydrophobic Coating of Expanded Perlite Particles by Plasma Polymerization,” Chemical Engineering Journal, V. 284, Jan. 2016, pp. 343-350.

20. Al-Kheetan, M. J.; Rahman, M. M.; Balakrishna, M. N.; and Chamberlain, D. A., “Performance Enhancement of Self-Compacting Concrete in Saline Environment by Hydrophobic Surface Protection,” Canadian Journal of Civil Engineering, V. 46, No. 8, Aug. 2019, pp. 677-686. doi: 10.1139/cjce-2018-0546

21. Yan, Q.; Hou, Y.; Luo, J.; Miao, H.; and Zhang, H., “The Exergy Release Mechanism and Exergy Analysis for Coal Oxidation in Supercritical Water Atmosphere and a Power Generation System Based on the New Technology,” Energy Conversion and Management, V. 129, Dec. 2016, pp. 122-130. doi: 10.1016/j.enconman.2016.09.091

22. Gao, H.; Liu, H.; Liao, L.; Mei, L.; Shuai, P.; Xi, Z.; and Lv, G., “A Novel Inorganic Thermal Insulation Material Utilizing Perlite Tailings,” Energy and Buildings, V. 190, May 2019, pp. 25-33. doi: 10.1016/j.enbuild.2019.02.031

23. Jia, G.; Li, Z.; Liu, P.; and Jing, Q., “Preparation and Characterization of Aerogel/Expanded Perlite Composite as Building Thermal Insulation Material,” Journal of Non-Crystalline Solids, V. 482, Feb. 2018, pp. 192-202. doi: 10.1016/j.jnoncrysol.2017.12.047

24. Ramakrishnan, S.; Wang, X.; Sanjayan, J.; Petinakis, E.; and Wilson,J., “Development of Thermal Energy Storage Cementitious Composites (TESC) Containing a Novel Paraffin/Hydrophobic Expanded Perlite Composite Phase Change Material,” Solar Energy, V. 158, Dec. 2017, pp. 626-635. doi: 10.1016/j.solener.2017.09.064

25. Cholewinski, A.; Trinidad, J.; McDonald, B.; and Zhao, B., “Bio-Inspired Polydimethylsiloxane-Functionalized Silica Particles—Epoxy Bilayer as a Robust Superhydrophobic Surface Coating,” Surface and Coatings Technology, V. 254, Sept. 2014, pp. 230-237.

26. Yan, Q.; Shen, X.; Luo, J.; Yan, H.; and Gao, H., “Experimental Study on Effective Thermal Conductivity of Building Insulation Materials,” Measurement Science and Technology, V. 30, No. 10, 2019, p. 105602. doi: 10.1088/1361-6501/ab1890

27. Kong, X.; Yao, C.; Jie, P.; Liu, Y.; Qi, C.; and Rong, X., “Development and Thermal Performance of an Expanded Perlite-Based Phase Change Material Wallboard for Passive Cooling in Building,” Energy and Buildings, V. 152, Oct. 2017, pp. 547-557. doi: 10.1016/j.enbuild.2017.06.067

28. Vogt, E., and Płachta, Ł., “The New Method of Modifying the Hydrophobic Properties of Expanded Perlite,” Energy & Fuels, V. 14, Mar. 2017, Article No. 02034, 6 pp.


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