Title:
Additives to Increase Carbonation Resistance of Slag Activated with Sodium Sulfate
Author(s):
Alaa M. Rashad
Publication:
Materials Journal
Volume:
119
Issue:
2
Appears on pages(s):
53-66
Keywords:
blast-furnace slag; carbonation depth; compressive strength; different additives; pH value; sodium sulfate
DOI:
10.14359/51734400
Date:
3/1/2022
Abstract:
The effect of a fixed ratio of different additives on the carbonation behavior of ground-granulated blast-furnace slag (shortened as slag) activated with a fixed concentration of Na2SO4 was investigated. Slag was activated by 1% (Na2O-equivalent) Na2SO4 (M0) and partially replaced with 10%, by weight, of one of the following additives: limestone powder (LS10), fly ash (FA10), portland cement (PC10), silica fume (SF10), metakaolin (MK10), and hydrated lime (HL10). The compressive strength values were measured and compared with those activated with the traditional common activators. After 28 days of curing, the pastes were exposed to 5% concentration of CO2 coupled with 20 ± 1°C and 65% surrounding temperature and relative humidity, respectively, for different durations of 2, 4, and 8 weeks. Compressive strength, pH value, and carbonation depth of carbonated specimens were determined and compared with noncarbonated ones exposed to the same conditions but at a natural CO2 concentration. The results were analyzed with special tools to determine the different phases. The results revealed that it is possible to increase the carbonation resistance of slag activated with Na2SO4 by using some additives. The specimens of LS10 exhibited the highest carbonation depth, while SF10 specimens exhibited the lowest carbonation depth. The remaining additives showed intermediate results between LS10 and SF10.