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Title: Fly Ash Reduces Harmful Chloride Ions in Concrete

Author(s): M. N. Haque, O. A. KayyaliI, and M. K. Gopalan

Publication: Materials Journal

Volume: 89

Issue: 3

Appears on pages(s): 238-241

Keywords: chlorides; concretes; fly ash; mixing; strength; superplasticizer; Materials Research

DOI: 10.14359/2565

Date: 5/1/1992

Abstract:
Concretes of high, low, and medium strength, with and without a fly ash and with and without a proprietary superplasticizer, were designed. The 75 x 150-mm concrete cylinders were cast and immersed in a sodium chloride salt solution of 19,350 ppm concentration. After 91 days of storage, the compressive strength of the concretes was determined and the chloride ions concentration in the specimens was evaluated by potentiometry. A decanted solution was used for the determination of the free chloride ions in the concrete specimens. The results suggest that adding fly ash to a plain concrete can significantly reduce the concentration of free chloride ions. A further addition of a superplasticizer in the fly ash concretes marginally enhanced the concentration of Cl- ions. An addition of the superplasticizer in the plain concretes also reduced the free chloride ions. Overall results suggest that a judicious use of fly ash in concrete making can decrease the incidence of chloride-induced corrosion of the reinforcement in concrete structures.


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