International Concrete Abstracts Portal

The presence of chloride ions is one of the most widespread causes of corrosion initiation in reinforcing steel in concrete. Trace chlorides present in cementitious materials or admixtures typically result in very low fresh chloride contents in normal-strength concrete that do not present a danger of corrosion. UHPC mixture designs, however, use much higher dosages of cementitious materials and admixtures that can result in non-negligible total fresh chloride contents. These high chloride values are likely to occur more frequently in the future as more UHPC mixtures are made with locally available materials and alternative cementitious materials and may result in concrete mixtures failing to meet specifications for fresh chloride content limits that are based on mixture proportions used in normal-strength concrete mixtures. UHPC and normal concrete samples were made without fibers and with increasing levels of internally admixed chlorides for four different levels of strength to determine chloride thresholds for internally added chlorides. The chloride threshold for fresh concrete was measured using a slightly modified version of the accelerated test EN 480-14. The water-soluble and acid-soluble chloride ion content of UHPC mixtures tested were measured according to ASTM C1218 and Florida Method FM 5-516 to determine the bound chlorides and fresh chloride limits for corrosion. The results demonstrate that the UHPC had ~ 25% higher chloride threshold than the control mixture when measured as an absolute content per unit volume of concrete. When the UHPC chloride content is normalized by mass of cementitious material, it was found that the amount needed to initiate corrosion may be lower than fresh chloride limits given in ACI-318 and ACI 222. Therefore, the ACI-318 water-soluble chloride limits as a % by mass of cementitious materials were found to be non-conservative for the two of the UHPC mixtures tested and should be re-examined for UHPC.

Maintaining workability can be a challenge when the total cement content of a concrete mixture is minimized in order to lower the carbon footprint. This is especially the case in everyday concrete where Portland cement content is mostly optimized for a targeted strength. Unlike high-performance or self-consolidating concretes (SCC) which commonly have high cement or cementitious materials contents, a minimum paste volume is generally required in normal strength concrete (NSC) mixtures to ensure adequate workability for the application and to be acceptable in the field. In this study, a new generation of rheology-modifying water-reducing admixture that improves concrete rheology is used to further reduce cement content and provide favorable workability for concrete applications. Comparisons to reference concrete are presented for their fresh and hardened properties, including plastic viscosity, dynamic yield stress, finishability, pumpability, and targeted strength. By combining concrete technology and this new rheology modifying water-reducing admixture, an economical, workable low-carbon concrete can be achieved.

Concrete has played a pivotal role in shaping the modern world’s infrastructure and the built environment. Its unparalleled versatility, durability, and structural integrity have made it indispensable in the construction industry. From skyscrapers to long-span bridges, water reservoirs, dams, and highways, the ubiquitous presence of concrete in modern society underscores its significance in global development. As we stand at the crossroads of environmental awareness and the imperative to advance our societies, the sustainability of concrete production and utilization is becoming a new engineering paradigm. The immense demand for concrete, driven by urbanization and infrastructure development, has prompted a critical examination of its environmental impact. One of the most pressing concerns is the substantial carbon footprint associated with traditional concrete production. The production of cement, a key ingredient in concrete, is a notably energy-intensive process that releases a significant amount of carbon dioxide (CO2) into the atmosphere. As concrete remains unparalleled in its ability to provide structural functionality, disaster resilience, and containment of hazardous materials, the demand for concrete production is increasing, while at the same time, the industry is facing the urgency to mitigate its ecological consequences. This special publication investigates the multi-faceted realm of concrete sustainability, exploring the interplay between its engineering properties, environmental implications, and novel solutions, striving to provide an innovative and holistic perspective. In recent years, the concrete industry has witnessed a surge of innovation and research aimed at revolutionizing its sustainability. An array of cutting-edge technologies and methodologies has emerged, each offering promise in mitigating the environmental footprint of concrete. Notably, the integration of supplementary cementitious materials, such as calcined clays and other industrial byproducts, has gained traction to reduce cement content while enhancing concrete performance. Mix design optimization, coupled with advanced admixtures, further elevates the potential for creating durable, strong, and eco-friendly concrete mixtures. Concrete practitioners will gain an advanced understanding of a wide variety of strategies that are readily implementable and oftentimes associated with economic savings and durability enhancement from reading these manuscripts. The incorporation of recycled materials, such as crushed concrete and reclaimed aggregates, not only reduces waste but also lessens the demand for virgin resources. Furthermore, the adoption of efficient production techniques, along with the exploration of carbon capture and utilization technologies, presents an optimistic path forward for the industry. This special publication aspires to contribute to the ongoing discourse on concrete sustainability, offering insights, perspectives, and actionable pathways toward a more environmentally conscious future.

Retarders are very important during the production of cement-based materials. The delay in setting might be helpful in avoiding negative phenomena related to the long-term transport of the fresh concrete mix, unforeseen breaks in the transport, or laying of concrete. These admixtures prevent the local temperature rise of the concrete, and thus the formation of cracks and also extent the workability. Set-retarders provide a correct development of the microstructure and the undisturbed setting and hardening of cement which lead to higher strengths of cement-based materials. An investigation of the cement mortar with potassium methylsiliconate (MESI) applied as set-retarding admixture was carried out. Siliconates are a highly alkaline water solution of methylsiloxane resin in the potassium or sodium hydroxide. The study involved the cement paste and mortar with three dosages (1%, 2%, and 3% per cement mass) of organosilicon admixture. So far, the siliconates were not applied as admixtures for cement mortar or concrete. The mortar specimens were tested for compressive strength after 1, 2, 7, and 28 days and frost resistance after 25 freeze-thaw cycles. Moreover, the impact of the methylsiliconate admixture on the hydration (by isothermal calorimetry) and setting time of the ordinary Portland cement was also studied.

Speed of production of units/structural elements and efficient use of resources are key driving forces in the precast/prestressed concrete industry and these factors significantly influence the concrete mixtures used by precast producers. For example, the production efficiencies provided by self-consolidating concrete (SCC) led to its rapid and widespread adoption in the precast industry. The development of newer high-performance concretes, such as ultra-high-performance concrete (UHPC), a continued shortage of skilled labor and societal demands with respect to sustainable concrete construction have increased the need for innovative concreting materials, in particular, chemical admixtures to address operational issues regarding concrete mixtures. Some of these issues include mixing time, flowability and flow retention, a high-quality surface finish, and very high-early strength development. In this paper, the authors present and discuss the use of innovative admixtures to address some of these performance issues; specifically, new high-range water-reducing admixtures that, respectively, provide fast wet-out of binder materials and rheology modification, nanotechnology-based strength-enhancing admixtures and a novel workability-retaining admixture.