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Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete: Proceedings of the Third International Conference presents the latest technological advances in the use of these extremely valuable mineral by products. This two-volume set of 83 papers explores in detail how you can conserve energy and resource while increasing your profitability. The first volume contains papers dealing with fly ash and natural pozzolans, and the second volume details the use of condensed silica fume and ferrous and non-ferrous slags. Note: The individual papers are also available as .pdf downloads.. Please click on the following link to view the papers available, or call 248.848.3800 to order. SP114

Paper presents the results of the tests conducted on reactive andesite produced to determine if Japanese fly ashes produced in Japan have an effect in controlling the alkali-aggregate reactions in concrete. Fourteen fly ashes produced were subjected to Japan Industrial Standard (JIS) alkali-silica reaction (ASR) mortar bar test (40 x 40 x 160 mm, alkali content in cement 1.2 percent, s/a = 2.25) with (c + f) ranging from 5 to 30 percent. With f/(c + f) at 20 percent or higher, all the mortar test bars incorporating fly ash had little expansion even after 6 months, but with f/(c + f) at 10 percent, different expansions were produced depending on the type used. The analysis of the data indicated that the component Na2Oeq of fly ash would accelerate the expansion while the component SiO2 will restrain the expansion. The controlling ability is also related to the alkali content of the cement: the greater the alkali from the cement and fly ash, the greater the quantity of fly ash required for preventing the expansion. An empirical formula expressing such a relationship has been derived. 123-389

A study was conducted to determine whether pulverized fuel ash, granulated blast furnace slag, and natural pozzolana contribute effective alkalies and whether such alkalies lead to alkali-silica reaction (ASR) damage. Mortar bars were prepared in accordance with ASTM C 227 but stored at 20 C, and using three factory-produced cements, three Type F pulverized fuel ashes, three blast furnace slags, and four natural pozzolans at three or four different levels of substitution. The reactive aggregate component was Beltane opal substituted at the pessimum level, as well as zero and three near-pessimum levels. The selection of the materials and their substitution levels were adjudged to represent as wide as possible present-day usage. Deleterious expansion defined as > 0.0 percent within 4 years was taken as the criterion of failure. The results have been applied to demonstrate the deduction of practical guidelines for the use of composite hydraulic binders in situations in which ASR is a consideration. Limiting total alkali contents of composite hydraulic binders as function of the substitution ratio of the three mineral additives are suggested. The analysis of the results demonstrates that if the effective alkalies derived from portland cement are taken as 100 percent, then those derived from pulverized fuel ash and natural pozzolana can be taken as 17 percent and those derived from blast furnace slag as 50 percent of total alkalies. There is also evidence of somem mineral additives, particularly at high substitution levels, not simply acting as dilutents but exhibiting a positive ASR-suppressive effect.

Cements consisting of 60 percent ground granulated blast furnace slag and 40 percent fly ash activated by 7 percent sodium hydroxide have been investigated. Various slags were used, including some laboratory-made synthetic slags. The influence of additives like superplasticizers and defoaming agents has been examined. The most favorable composition with respect to strength development has been subjected to a durability testing program. A negative aspect appeared to be the carbonation resistance, which is low in comparison with portland cement. Carbonation leads to a decrease in strength. Other properties were favorable.

Durability properties of concrete and mortar based on a special type of alkali-activated slag called F-cement have been studied. The microstructure was found to possess a high occurrence of microcracks that had an obvious influence on the flexural strength and rate of carbonation. The rate of chloride-ion diffusion was about 30 times lower than in the portland cement concrete. Salt scaling was found to depend solely on the water-to-binder ratio and is independent of the air content. Early freezing takes place when the strength exceeds 5 MPa, and F-mortar shows high chemical resistance against solutions of sodium, calcium, and magnesium chloride.